Graphene oxide/polyurethane‐based composite solid–solid phase change materials with enhanced energy storage capacity and photothermal performance

Abstract

Summary The preparation of phase change materials (PCMs) with high energy storage, thermal conductivity, and photothermal conversion capability is essential for improving solar energy conversion and storage. In this study, graphene oxide (GO) was incorporated into polyurethane (PU) prepared from 4,4′‐diphenylmethane diissyanate (MDI) and polyethylene glycol (PEG). PU/GO composite PCMs exhibit enhanced thermal conductivity (0.972Wm−1 K−1) because the isocyanate in MDI can covalently graft with GO. The composite solid–solid PCMs has outstanding stability and thermal reliability. It can stay stable at 80°C for more than 15 min without leaking and has good thermoregulation regulation performance. The thermal energy storage density and photothermal conversion efficiency of PU/GO increase as the amount of PEG and GO increases. The PU/GO composite with 89 wt% PEG and 1.72 wt% GO has a phase change enthalpy of 150.7 J/g and a high photothermal conversion efficiency (95.3%). The composite PU/GO solid–solid PCMs have great potentials for effective energy storage and solar energy utilization.

Photothermal Conversion of Hydrogel‐Based Biomaterial

“…The main photo-thermal conversion agents of typical hydrogels for photo-thermal conversion materials include metal nanoparticles such as Au, [38][39][40] Ag, [41][42] Cu, [43][44] and metal ion compounds, semiconductor materials such as TiO 2 , [45,46] CuS, [47,48] MoS 2 [49][50] containing transition metal elements, inorganic carbon materials mainly composed of graphene oxide [51][52] and carbon nanotubes, [53][54] as well as organic polymer materials such as polydopamine [55][56] and polythiophene (Figure 3). [57] The advantages and disadvantages of these different types of photothermal agents are summarized in Table 1.…”