Topological defects can play an important role in cosmology. In this short contribution I will discuss a less explored effect that arises in the context of first order phase transitions, by which defects can act as impurities catalysing the decay of the false vacuum. This dynamics actually takes place in one of the simplest extensions of the Standard Model, the xSM, where domain wall configurations associated to the new singlet scalar are shown to enhance the tunneling rate. This dramatically changes the way the electroweak phase transition proceeds, with implications for the corresponding spectrum of gravitational waves.