Ultra-narrow spectral features are desirable for a broad range of applications, from precision spectroscopy to atomic clocks to slow-light and microwave photonics, and are conventionally realized using either ultrahigh-Q resonant structures or atomic resonances. Ultrahigh-Q structure often involves microfabrication, and suffers from loss mechanisms and manufacturing variations that cannot be easily compensated, whereas atomic resonances suffer from signal attenuation and tunability is a challenge. Here, we propose an entirely new way to achieve a sub-MHz and tunable spectral feature in a resonator-free gain medium, exploiting polarization pulling in a medium with frequency dependent polarization eigenmodes. To demonstrate a specific realization, we use Brillouin gain in a commercial spun fiber and experimentally achieve a 0.72 MHz spectral dip, which is to our knowledge, the narrowest spectral Brillouin feature ever reported. Furthermore, the simulation shows that the dip linewidth can be reduced to <0.1MHz, equivalent to a Q of almost 2 billion, by optimizing the birefringence and spun rate of the fiber. We also show that the linewidth, depth, and spectral location of this dip are all tunable on demand by controlling the pump frequency, pump power, and the input polarization of the signal. Its simplicity in implementation and broad applicability, its ultra-narrow linewidth, its tunability makes this approach extremely attractive for applications such as high precision metrology and microwave photonics.