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The evidence for imitation coinage found on the Gallo‐Roman site of Châteaubleau (Seine‐et‐Marne, France) has been attested for several years. Successive excavations and findings related to the production of imitation coins, both struck and cast, have revealed major minting activity during the second half of the third century CE. This paper presents the study of 11 archaeological samples issued from this counterfeiting workshop site, which is today considered the most important in the north‐western provinces of the Roman Empire. These samples, which correspond to different stages in the production chains leading to coins, mainly radiates (antoniniani, double sestertii), were characterized by metallography, energy‐dispersive X‐ray fluorescence (EDXRF), scanning electron microscopy with energy‐dispersive spectroscopy (SEM‐EDS) and the Vickers hardness test, in order to understand the different manufacturing processes, especially the ‘rod to coin’ one. This project is divided into two parts. The first, which is the subject of this paper, focuses on the chemical and metallurgical study of the archaeological artefacts. This has enabled us to identify and characterize the manufacturing processes thanks to the highly characteristic microstructure of the samples from the rod‐to‐coins process. Some of the cylinders derived from this process were also silvered by plating a foil of silver or silver–copper on a flan of pure copper in order to obtain irregular radiates. As regards fake double sestertii, several manufacturing techniques were identified: direct moulding of coins in stacked terracotta moulds, the casting of flans to strike double sestertius and the cutting of flans from metal plate is also a technique used in Châteaubleau. Characteristic composition and microstructures were also observed in these samples. This paper will be followed by a second focused on two experimental archaeology sessions carried out in order to reproduce the process ‘from rod to coins’ and then to compare the reproduced samples with the archaeological samples.
The evidence for imitation coinage found on the Gallo‐Roman site of Châteaubleau (Seine‐et‐Marne, France) has been attested for several years. Successive excavations and findings related to the production of imitation coins, both struck and cast, have revealed major minting activity during the second half of the third century CE. This paper presents the study of 11 archaeological samples issued from this counterfeiting workshop site, which is today considered the most important in the north‐western provinces of the Roman Empire. These samples, which correspond to different stages in the production chains leading to coins, mainly radiates (antoniniani, double sestertii), were characterized by metallography, energy‐dispersive X‐ray fluorescence (EDXRF), scanning electron microscopy with energy‐dispersive spectroscopy (SEM‐EDS) and the Vickers hardness test, in order to understand the different manufacturing processes, especially the ‘rod to coin’ one. This project is divided into two parts. The first, which is the subject of this paper, focuses on the chemical and metallurgical study of the archaeological artefacts. This has enabled us to identify and characterize the manufacturing processes thanks to the highly characteristic microstructure of the samples from the rod‐to‐coins process. Some of the cylinders derived from this process were also silvered by plating a foil of silver or silver–copper on a flan of pure copper in order to obtain irregular radiates. As regards fake double sestertii, several manufacturing techniques were identified: direct moulding of coins in stacked terracotta moulds, the casting of flans to strike double sestertius and the cutting of flans from metal plate is also a technique used in Châteaubleau. Characteristic composition and microstructures were also observed in these samples. This paper will be followed by a second focused on two experimental archaeology sessions carried out in order to reproduce the process ‘from rod to coins’ and then to compare the reproduced samples with the archaeological samples.
At the Hwangnyongsa temple site, which was founded in 633, at Dongdaebong Mountain in Korea, a large number of gilt-bronze artefacts have been excavated. Optical microscopy, X-ray fluorescence, scanning electron microscopy, energy dispersive X-ray spectroscopy, focused ion beam and transmission electron microscopy were used to identify the structure of specimen and impurities. This article investigated the impurities and copper grains in bronze Buddha robes from the Hwangnyongsa temple site to determine the ancient bronze craft technology in the Unified Silla period (seventh–tenth). The XRF results of the specimens indicated that they were made using an alloy of copper and tin, and gold plating was only added on the front side. The microstructure of the specimen was confirmed to be a recrystallized equiaxed hexagonal structure with twins and impurities. The EDS results of the impurities indicated the molar ratio of Cu:S was 2:1, and the electron diffraction pattern substantiated this result by indicating Cu2S (JCPDF 33-0490). The surface of the specimen consisted of a highlead layer and copper grains. It was hypothesized that the copper grains were formed by the reaction of Pb with the matte (Cu2S) during casting. Lead with black gas would aid in the production of high-quality bronze. The copper grains used were found in Silla, as they have been detected in Koryo bronze artefacts. Hence, it is plausible that the ancient artisans knew that lead provided good bronze quality during the casting process.
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