Green and facile synthesis of EuBDC coordination polymer: Effects of ultrasound and stabilizing agent on morphological, structural and photophysical properties

Calado, Claudia Manuela Santos; Silva, Kleyton Ritomar Monteiro da; Santos, Thatiane Veríssimo dos; Viana, Rodrigo da Silva; Meneghetti, Simoni Margareti Plentz; Barbosa, Cintya D' Angeles do Espirito Santo

doi:10.1016/j.optmat.2022.112107

Cited by 2 publications

(2 citation statements)

References 37 publications

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“…Several groups are currently working in that very competitive field, playing with the choice of the ligand, − the choice of the metallic centers, , or the shaping of the microcrystalline powders. , However, it is difficult to compare the luminescence efficiencies of the different materials with each other . Indeed, most often, only the quantum yield, Φ λ (relationship ), is reported, and there is no information about the brightness. normalΦ λ = normaln normalu normalm normalb normale normalr .25em normalo normalf .25em normale normalm normali normalt normalt normale normald .25em normalp normalh normalo normalt normalo normaln normals normaln normalu normalm normalb normale normalr .25em normalo normalf .25em normala normalb normals normalo normalr normalb normale normald .25em normalp normalh normalo normalt normalo normaln normals …”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers

et al. 2022

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Measuring the luminance of lanthanide-based coordination polymers under UV excitation is of prime importance for many technological applications. This study highlights that the quantum yield gives no information about the luminescence intensity of a solid-state compound. Indeed, compounds with high quantum yield can actually be poorly luminescent. Therefore, a brightness calculation or a luminance measurement are mandatory for a quantitative estimation of the luminescence intensity. The calculated brightness appears to be a convenient quantitative parameter for the estimation of the luminescence intensity in the infrared domain, in which luminance is senseless. It is also a useful parameter in the visible domain, but one must keep in mind that only compounds with similar colorimetric coordinates can be compared. For comparing the luminescence intensities of compounds that exhibit different emission colors, the luminance measurement seems to be the most efficient method. A home-made setup that allows this measurement with high reproducibility is described in detail. The luminance of several lanthanide-based coordination polymers with benzene-poly-carboxylate ligands is measured, and the results are compared with brightness and quantum yield measurements. A standard is suggested for calibration.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers

et al. 2022

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Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands

Tai

Wang

et al. 2023

Bull. Chem. React. Eng. Catal.

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A new Gd(III) coordination polymer, {[Gd(L1)3(H2O)2]∙L2}n (1) (HL1 = 6-phenylpyridine-2-carboxylic acid, L2 = 4,4’-bipyridine) was synthesized using 6-phenylpyridine-2-carboxylic acid, 4,4’-bipyridine, NaOH and GdCl3∙6H2O. The structure of Gd(III) coordination polymer has been characterized by IR and X-ray single crystal diffraction. The result of single crystal analysis indicates that fundamental unit of Gd(III) coordination polymer contains one Gd(III) ion, three L1 ligands, two coordinated water molecules and one uncoordinated 4,4’-bipyridine. In 1, the Gd(III) ion is eight-coordinated and surrounded by six O atoms from three L1 ligands and two O atoms from two coordinated water molecules, respectively. The complex 1 exhibits 1D chained structure by the bridging interactions of two carboxyl-oxygen atoms and O−H∙∙∙N hydrogen bonds interactions. The 1D chains are further connected by - stacking interactions to form 3D network architecture. The photocatalytic CO2 reduction activity of complex 1 has also been investigated. The complex 1 exhibits good CO2 reduction activity. With the increase of time, the yield of CO from 18.2 mmol/g in the first hour to 60.3 mmol/g in the third hour. And the CO selectivity has reached 100%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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Green and facile synthesis of EuBDC coordination polymer: Effects of ultrasound and stabilizing agent on morphological, structural and photophysical properties

Cited by 2 publications

References 37 publications

Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers

Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers

Synthesis, Structural Characterization and Photocatalytic CO2 Reduction Activity of a New Gd(III) Coordination Polymer with 6-Phenylpyridine-2-carboxylic acid and 4,4’-Bipyridine Ligands

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