Green deep eutectic solvent assisted liquid–liquid microextraction procedure for Sunset Yellow dye in effervescent vitamin C tablets

Dalmaz, Aslıhan; Özak, Sezen Sivrikaya

doi:10.1007/s13738-021-02454-y

Cited by 20 publications

(2 citation statements)

References 48 publications

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“…Deep eutectic solvents (DESs) can be obtained by mixing at least one hydrogen bond acceptor (HBA) and hydrogen bond donor (HBD) at the appropriate temperature. In addition to the advantages of physicochemical properties such as density, surface tensions, refractive index, viscosity, and conductivity, it also has advantages such as low ecological footprints, cost-effective and easy synthesis [27][28][29][30][31][32][33][34].…”

Section: Introductionmentioning

confidence: 99%

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Özalp

Gümüş

Soylak

2023

J of Separation Science

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An NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was synthesized for extraction and determination of Rhodamine (Rh) 6G from environmental and cosmetic samples. The deep eutectic solvent (DES) was prepared by mixing choline chloride and urea in a mole ratio of 1:2. NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was synthesized using the impregnation method at a ratio of 60:40 (w/w). The optimum conditions were determined after NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) characterization was performed. The optimum conditions were determined as pH 8, adsorbent amount of 15 mg, total adsorption‐desorption time of 6 min, and enrichment factor of 20. The recovery values of the solid‐phase extraction method for water and cosmetic samples under optimum conditions were between 95% and 106%. NH2‐MIL‐53(Al)‐DES(ChCl‐Urea) nanocomposite was an economically advantageous adsorbent because of its reusability of 15 times. All analyses were performed using the ultraviolet‐visible spectrophotometer. The linear range, limit of detection, and limit of quantification of the method were 100–1000, 9.80, and 32.68 μg/L, respectively. The obtained results showed that the synthesized nanocomposite is a suitable adsorbent for the determination of Rh 6G in water and cosmetic samples. The real sample applications were verified with the high‐performance liquid chromatography system.

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Section: Introductionmentioning

confidence: 99%

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Özalp

Gümüş

Soylak

2023

J of Separation Science

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“…For instance, choline chloride or vitamin B 4 is introduced as the most used HBA, whereas amino acids, carboxylic acids, urea, ethylene glycol, glycerol, and sugars have been used as HBD [24]. DESs show the characteristic of high purity and eco-friendly [25], which have been used for the extraction and microextraction of synthetic dyes: simultaneous identifcation of eight synthetic dyes [26], determination of some red dyes [27], and determination of sunset yellow dye [28].…”

Section: Introductionmentioning

confidence: 99%

Simultaneous Preconcentration of Fast Green FCF and Rhodamine B Using Deep Eutectic Solvent and Determination via High-Performance Thin Layer Chromatography

Karami,

Shokrollahi

2023

Journal of Analytical Methods in Chemistry

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The aim of the current investigation is the development of a green, quick, easy, and accurate method for simultaneous preconcentration of fast green FCF (FG) and rhodamine B (Rh B) using a deep eutectic solvent (DES). Then, the high-performance thin layer chromatography (HPTLC) technique was used for the determination of analytes. Decanoic acid and tetrabutylammonium bromide were chosen as the components of DES. HPTLC analysis was performed on an aluminum plate silica gel 60 F254. Methanol-ammonia and ethyl acetate were selected as the mobile phase. Scanning of the plates was accomplished by scanner 3. Effective parameters on the preconcentration process such as concentration of salt, volume of DES, stirrer time, and pH were investigated via central composite design (CCD). Data validation demonstrated good repeatability. The limit of detection for FG and Rh B was obtained as 0.08 and 0.01 µg·mL−1, respectively. The enrichment factor for FG and Rh B was achieved as 7.43 and 10.77, respectively. The linear ranges for FG and Rh B were acquired as 0.10–1.20 and 0.05–1.20 µg·mL−1, respectively. The preconcentration factor for both analytes was 21.66. Finally, the proposed method was successfully used for the quantitation of FG and Rh B in pastille and lipstick.

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Developing of an eco-friendly liquid–liquid microextraction method by using menthol-based hydrophobic deep eutectic solvent for determination of basic fuchsin dye: assessment of the greenness profile

Aydin,

Alkan,

Dönmez

2024

Environ Monit Assess

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Green deep eutectic solvent assisted liquid–liquid microextraction procedure for Sunset Yellow dye in effervescent vitamin C tablets

Cited by 20 publications

References 48 publications

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Metal‐organic framework functionalized with deep eutectic solvent for solid‐phase extraction of Rhodamine 6G in water and cosmetic products

Simultaneous Preconcentration of Fast Green FCF and Rhodamine B Using Deep Eutectic Solvent and Determination via High-Performance Thin Layer Chromatography

Developing of an eco-friendly liquid–liquid microextraction method by using menthol-based hydrophobic deep eutectic solvent for determination of basic fuchsin dye: assessment of the greenness profile

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