Green solvents in organoselenium chemistry

Kostić, Marina D.; Divac, Vera M.

doi:10.1007/s10311-018-00848-8

Cited by 13 publications

(9 citation statements)

References 71 publications

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“…The transformations include direct selenylations, selenocyclizations, selenoxide eliminations and 2,3‐sigmatropic rearrangements [34] . Researchers have successfully reviewed staggering progress being made in the direction of organoselenium compounds focussing on their catalytic efficiency in various significant reactions, [34–38] greener prospects [39] and therapeutic significance of different class of organoselenium compounds [16,40] …”

Section: Overview On Selenium‐catalyzed/selenium Incorporating Transfmentioning

confidence: 99%

“…The transformations include direct selenylations, selenocyclizations, selenoxide eliminations and 2,3-sigmatropic rearrangements. [34] Researchers have successfully reviewed staggering progress being made in the direction of organoselenium compounds focussing on their catalytic efficiency in various significant reactions, [34][35][36][37][38] greener prospects [39] and therapeutic significance of different class of organoselenium compounds. [16,40] This review focuses on the recent progress made in the organoselenium chemistry in last 3 years which has not been covered in earlier reviewed content entailing the advances made in the field.…”

Section: Overview On Selenium-catalyzed/selenium Incorporating Transfmentioning

confidence: 99%

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Insights into the Recent Synthetic Advances of Organoselenium Compounds

2021

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The ever-growing interest for organoselenium compounds amongst the chemists has made commendable impact in the field of medicinal chemistry, material chemistry, chemical biology and biochemistry. Researchers have progressively contributed in the development of organoselenium compounds over the years which has been periodically reviewed. On the similar note, this review attempts at providing an overview of the recent advances made in organoselenium chemistry while covering their catalytic indulgence in different transformational approaches, their role in asymmetric synthesis, and synthetic approaches steering their synthesis. These approaches encompass selenofunctionalization and/or cyclization, electrochemical selenylation, bromolactonization, [2,3]-or [1,2]-sigmatropic rearrangement reactions among others. Herein, we have focused on the synthetic approaches developed for the past three years that have not been covered in previously reviewed scientific material. With the knowledge of the recent progress covered, this review could contribute towards future development of organoselenium compounds along with the improvement of the current status.

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Section: Overview On Selenium‐catalyzed/selenium Incorporating Transfmentioning

confidence: 99%

Section: Overview On Selenium-catalyzed/selenium Incorporating Transfmentioning

confidence: 99%

Insights into the Recent Synthetic Advances of Organoselenium Compounds

2021

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“…In comparison with ILs, deep eutectic solvents (DESs) have lower costs and an easier synthesis process, being produced with high purity, are less harmful for the environment and present less toxicity (Benvenutti et al 2019;Kostić and Divac 2019). DESs are characterized by a lower melting point than the initial constituents (Florindo et al 2017;Krishnan et al 2020).…”

Section: Non-conventional Solventsmentioning

confidence: 99%

Biorefinery of marine macroalgae into high-tech bioproducts: a review

et al. 2020

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Pollution and climate change induced by fossil fuel usage are calling for the development of a circular bioeconomy based on carbon neutral resources such as marine macroalgae, also named seaweeds. Macroalgal biomass can generate biofuels and valuable bioproducts such as hydrocolloids and other unique biomolecules. Biorefinery of marine macroalgae involves a minimum use of energy and chemicals, and low waste generation, as demonstrated in recent laboratory-scale studies. Here, we review biorefinery of marine macroalgae with focus on non-energy bioproducts and advances in the separation of biomolecules. We found that metabolites with bioactive properties are in high demand for food, cosmetic, medicine and pharmaceutical industries. These metabolites can be obtained together with energy products to improve macroalgae valorization. Emerging extraction methods facilitate the generation of more qualitative bioproducts in higher yields with less energy.

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“…[27][28][29][30][31] The development of novel routes towards organoselenium derivatives is, therefore, highly desirable. 16,32 In this scenario, we recently reported new synthetic procedures for the synthesis of selenium-containing functionalized small molecules under mild conditions. [33][34][35] However, despite the interest in the synthesis of organoselenium compounds, to the best of our knowledge, no reports are available on the -metalation of selenyl derivatives.…”

confidence: 99%