“…[69][70][71] Mineral acids, such as H2SO4, H3PO4, HCl, and p-toluene sulphonic acid (PTSA), 72 were strongly employed in the esterification for their high yields (>95 %) 73 , fast reaction rates, and low cost, but their downstream drawbacks made it mandatory their replacement, even though there were some efforts to develop acid more sustainable as the bio-glycerol derived carbon sulfonic-acid. 74 Up to now, various heterogeneous catalysts, such as zeolites, 75-77 heteropolyacids, 78,79 acid ion exchange resins, 71,80,81 nanostructured solid acid, 82 sulfonic acid-functionalized organic polymer, 83 silica based, [84][85][86] metal oxide, zirconia based, 87 nano-material catalysts [88][89][90][91] , ionic liquids 92 and biocatalysts [93][94][95] have been efficiently used to produce alkyl levulinates from LA (Table 3). Zeolites are widely used as solid acid catalysts and ionexchangers in several processes thanks to the possibility of finetuning their properties.…”