Green Synthesis of Enaminones Catalyzed by ZSM-5

Abstract

It was found that ZSM-5 as a green catalyst could efficiently catalyze the reaction of various primary amines with α,β-dicarboxyl compounds to afford β-enaminones in good yields at room temperature. The method provides a novel, simple and convenient route to substitute β-enaminones from primary amines and α,β-dicarboxyl compounds. The catalyst could also be recovered easily.

Regioselective Preparation of Enaminone via Enol Methyl Ether of 3-Acetyl-2-butenolide and Different Amines

“…从上面的结果分析可以看到, 中间体 8a～8d 与有 机胺类化合物反应生成了稳定的烯胺酮结构. 烯胺酮是 非常有用的有机合成中间体 [17～23] , 近年来相继报道了 一些结构相对复杂的烯胺酮衍生物具有不同的生物活 性 [5,18～23] [17,24,25] a These results will be presented in the other paper due to opening of lactone ring and forming novel structures. 16b,26] .…”