2010
DOI: 10.1016/j.poly.2009.07.038
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Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds

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Cited by 60 publications
(19 citation statements)
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“…The Ni−C (1.876 Å) and Ni−Cl (2.1903 Å) bond lengths are comparable to those reported for related Ni(II)‐POCOP pincer complexes, whereas the M−P distances exhibited values in the range of 2.1432–2.1633(10) Å. The distances and angles of Ni(II)‐POCOP‐1 and Ni(II)‐POCOP‐2 are comparable with the interatomic distances and angles in closely related structures [13a,21] . Attempts to synthesize the corresponding Pd‐POCOP pincer complexes under different reaction conditions were unsuccessful.…”
Section: Resultssupporting
confidence: 72%
“…The Ni−C (1.876 Å) and Ni−Cl (2.1903 Å) bond lengths are comparable to those reported for related Ni(II)‐POCOP pincer complexes, whereas the M−P distances exhibited values in the range of 2.1432–2.1633(10) Å. The distances and angles of Ni(II)‐POCOP‐1 and Ni(II)‐POCOP‐2 are comparable with the interatomic distances and angles in closely related structures [13a,21] . Attempts to synthesize the corresponding Pd‐POCOP pincer complexes under different reaction conditions were unsuccessful.…”
Section: Resultssupporting
confidence: 72%
“…This has led to the development of cheaper nickel-based catalysts for this important catalytic reaction. Pincer complexes of palladium are among the best catalysts for Suzuki-Miyaura couplings [106] because of the physical and electronic properties that the pincer complexes have, and therefore, it is a natural extension to test their nickel counterparts. However, it is certainly curious that not many POCOP-Ni complexes have been tested in this reaction.…”
Section: Suzuki-miyaura Couplingsmentioning
confidence: 99%
“…In all complexes the P(1)eMeP(2) and C ipso eMeCl angles are smaller than 180 , which is typical for ECE-pincer complexes (see Fig. 2) [15].…”
Section: X-ray Diffraction Studiesmentioning
confidence: 72%