2023
DOI: 10.1002/chem.202302618
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Group I Alkoxides and Amylates as Highly Efficient Silicon–Nitrogen Heterodehydrocoupling Precatalysts for the Synthesis of Aminosilanes

Matthew B. Reuter,
Diego R. Javier‐Jiménez,
Claire E. Bushey
et al.

Abstract: Group I alkoxides are highly active precatalysts in the heterodehydrocoupling of silanes and amines to afford aminosilane products. The broadly soluble and commercially available KOtAmyl was utilized as the benchmark precatalyst for this transformation. Challenging substrates such as anilines were found to readily couple primary, secondary, and tertiary silanes in high conversions (> 90%) after only 2 h at 40 °C. Traditionally challenging silanes such as Ph3SiH were also easily coupled to simple primary and… Show more

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