Growth and characterization of cadmium magnesium tetra thiocyanate crystals

Growth and characterization of nonlinear optical bimetallic thiocyanate complex of MCCTC crystal

“…The band at 2824 cm À1 confirms the stretching vibration (Hg-Cl) to prove the existence of Cl in the crystal. In the spectrum of MCCTC, the band 2d(NCS) appearing at 915 cm À1 confirms the metal nitrogen and metal sulfur coordination in its structure, which is a common feature in bimetallic thiocyanate crystals [13,14].…”

“…3. In general, for bimetallic coordination compounds, the CQN stretching vibration often lies higher than 2100 cm À1 , S stretching vibration lies between 860 and 780 cm À1 (N-bonding) or 720-690 cm À1 (S-bonding) and (SCN) bending vibration lies at 480 cm À1 (N-bonding) or 420 cm À1 (S-bonding) [13]. A comparison of IR spectral data of MCCTC with other bimetallic counter parts like CMTC and MMTC is presented in Table 2.…”

Growth and characterization of organometallic nonlinear optical TMTM single crystals

“…5 and 6. The thermal analysis of metal thiocyanate complexes has been reported by several researchers [5,8,[14][15][16][17][18]. In the present work, the thermal decomposition of TMTM can be better understood by the following reasonable equations:…”

Studies on the growth, optical, thermal and dielectric aspects of a proton transfer complex – Dimethyl amino pyridinium 4-nitrophenolate 4-nitrophenol (DMAPNP) crystals for non-linear optical applications

“…The equilibrium solubility and its temperature dependence are essential for solution growth. The data from the solubility curve will suffice to start growing fair quality single crystals [18]. The solubility of DMAPNP in acetone was assessed as a function of temperature in the temperature range 30-50°C.…”