This study aimed to (a) analyze the influence of pyrolysis temperature on pistachio shell-based biochar (PSB) properties and (b) assess the PSB effect on green bell pepper (Capsicum annuum L.) growth. Pyrolysis experiments were conducted at different temperatures, determining 450 °C as optimal for soil amendment. The effect of PSB addition at different mass ratios was analyzed considering the physicochemical properties of the mixtures and the agronomic parameters of green bell pepper plants and fruits under greenhouse conditions. Results demonstrated enhancements in soil properties upon biochar incorporation, including a decrease in pH by 1%, a decrease in electrical conductivity (EC) by 4–14%, and increases in cation exchange capacity (CEC) by 4–8%, organic matter (OM) and organic carbon (OC) by 100–200%, and total nitrogen (TN) by 35%, relative to unamended soil. Agronomic variables revealed improvements, particularly during the reproductive and maturity stages, with plants treated with 1% biochar (SB1) exhibiting enhanced growth and chlorophyll content, alongside increased flower and fruit yields. Notably, the 2% biochar treatment (SB2) yielded superior fruit weight and length results, suggesting the potential for biochar to enhance both the quality and quantity of green bell pepper fruits, thereby contributing to sustainable agricultural practices.