2007
DOI: 10.1143/jjap.46.4359
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Growth and Field Emission Characteristics of Carbon Nanotubes Using Co/Cr/Al Multilayer Catalyst

Abstract: A multilayer catalyst, Co/Cr/Al, was employed to synthesize carbon nanotubes (CNTs) at atmospheric pressure by thermal chemical vapor deposition (thermal CVD). The relative growth rates, calculated on the basis of the average lengths of nanotubes grown at different temperatures, were utilized to estimate an activation energy of 0.84 eV for the multilayer catalyst. Such a low activation energy implies that the nucleation and growth of nanotubes could be effectively enhanced via the multilayer catalyst due to th… Show more

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Cited by 10 publications
(4 citation statements)
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“…The codeposited Co-Ti layer suppresses the coalescence of Co nanoparticles in order to obtain uniformly distributed CNT pillars. 22) The diameter and interpillar spacing of CNT pillars are set to 50 and 30 m, respectively. Finally, CNT pillars are grown on a patterned catalyst by thermal CVD.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…The codeposited Co-Ti layer suppresses the coalescence of Co nanoparticles in order to obtain uniformly distributed CNT pillars. 22) The diameter and interpillar spacing of CNT pillars are set to 50 and 30 m, respectively. Finally, CNT pillars are grown on a patterned catalyst by thermal CVD.…”
Section: Methodsmentioning
confidence: 99%
“…The optimal CNT pillar has a highly uniform emission area and a high current density owing to the uniform length of the CNT synthesized using the Co-Ti/Ti codeposited catalyst layer and the better adhesion between the CNT and substrate. 22)…”
Section: E Pe Ro-r E Pe Ro-l E Pe Rm-r E Pe Rm-l E Pe C-r E Pe C-l E ...mentioning
confidence: 99%
“…The codeposited Co-Ti layer can suppress the coalescence of Co nanoparticles, resulting in uniformly distributed CNT pillars. 11) Finally, CNTs are grown on the patterned catalysts as the pillar structures by thermal CVD. For the thermal CVD procedure, first, the catalytic metal is pretreated with hydrogen at 600 °C for 5 min at a flow rate of 300 sccm to produce nanoparticles.…”
Section: Experiments Proceduresmentioning
confidence: 99%
“…The SEM image in figure 4(a) shows that they have a spaghetti-like appearance. This kind of arrangement is preferred over well-aligned fibers since it has been shown that they have better field emission properties [27]. The TEM image in figure 4(b) shows that the nanofibers are not completely hollow.…”
Section: Carbon Nanofibersmentioning
confidence: 99%