Growth and properties of dichloro bis(triphenylphosphine oxide) zinc(II), a novel nonlinear optical crystal

Crystal growth and characterization of dibromo bis(triphenylphosphine oxide) cadmium (II)

“…A ceramic crucible was employed for heating the sample and the analyses was carried out in an atmosphere of nitrogen at a heating rate of 10 K/min in the temperature range 313-1473 K. The initial mass of the material subjected to the analysis was 4.74 mg. Thermal studies show that the crystal is stable without decomposition upto $573 K and the endothermic peak observed at $493 K represents the melting point of CdBr 2 (TPPO) 2, which is almost equal to the melting point of ZnCl 2 (TPPO) 2 [18]. Further the endothermic peak observed at $ 723 K shows that the material undergoes irreversible transition at this temperature.…”

“…The peak at $3455 cm À 1 is assigned for the stretching vibrations of the O-H bond of water molecules absorbed by KBr. The vibrational frequencies of CdBr 2 (TPPO) 2 are compared with that of the FTIR spectrum of ZnCl 2 (TPPO) 2 in Table 2 [18]. Hydrogen bonding originates from the hydrogen donor (A-H) and a region of high electron density acceptor atom (B), leading to the variation of HyB distance from the van der Walls radii of the isolated H and B atoms.…”

Growth and Characterization of Dichloro Tris(Triphenyl Phosphine Oxide)Cadmium(II) —Second Harmonic Generation from a Centrosymmetric Crystal

“…The peak at ~3456 cm −1 is assigned for the stretching vibrations of the O-H bond of the water molecules absorbed by KBr. The vibrational frequencies of CdCl 2 (TPPO) 4 are compared with that of the FTIR spectrum of ZnCl 2 (TPPO) 2 [5] and CdBr 2 (TPPO) 2 [6] in Table 2.…”

Green Phosphorescent Zn(II) Halide Complexes with N,N,N′,N′‐tetramethyl‐P‐indol‐1‐ylphosphonic Diamide as Ligand

“…The literature outcomes are limited to the use of triphenylphosphine oxide, [12] but no luminescent study on the corresponding Zn(II) complexes was ever described. It is however worth noting that [ZnCl 2 (O=PPh 3 ) 2 ] exhibited non‐linear optical properties [13] . For what concerns phosphoramide Zn(II) complexes, some tetrahedral homoleptic complexes were isolated [14] .…”

“…It is however worth noting that [ZnCl 2 (O=PPh 3 ) 2 ] exhibited non-linear optical properties. [13] For what concerns phosphoramide Zn(II) complexes, some tetrahedral homoleptic complexes were isolated. [14] Hexamethylphosphoramide is present in the coordination sphere of a dinuclear zinc(II) alkoxide-phenoxide-ketoiminate complex [15] and the interactions in solution of zinc(II) halides and perchlorate and of tetraphenylporphirinatozinc with hexamethylphosphoramide were investigated.…”