The poly(phenlene sulfide)(PPS)/carbon nanotubes (CNTs) composite was prepared by plastic pressure moulding of mixture of PPS and CNTs mixed by ball mill. The structure, elcctrical conductivity and mechanical properties of the composite were studied in detail. The effect of content of CNT on mechanic properties and conductivity of composite was carried out, repectivly. The SEM characterization indicates that CNTs were dispersed uniformly in the PPS matrix, which leads to a remarkable improvement in mechanical properties of composite. Compared with the those of neat PPS, both the tensile strength and impact strength of the composite increase with content of CNTs. and the addition of CNT increases the conductivity of the composites dramatically.