“…It is to be noted the changes occurred in the lattice parameters, in particular c, and the crystallite size. The recorded changes may be explained by the change of the ionic radii in different coordination states (Al-Salman and Abdullah, 2013; Fu et al, 2013;Karak et al, 2015;Karzazi et al, 2015;Poongodi et al, 2015;Xu and Cao, 2009), i.e. : in octahedral coordination the ionic radius of Co 2+ is 0.78 Å, whereas that of Zn 2+ is 0.74 Å, which can lead to decreasing of parameter c, while in tetrahedral coordination the ionic radius of Co 2+ is 0.58 Å, whereas that of Zn 2+ is 0.60 Å, which can lead to parameter c increasing.…”