First and foremost I offer my sincerest gratitude to my supervisor, Associate Professor Rusli, who has supported me throughout my thesis with his encouragement and knowledge. I am grateful for being given the opportunity to be his PhD student and for the genuine support he provided me with at each and every step of this journey. Every meeting with Professor Rusli for me was a source of new ideas, hope and motivation to move forward, to face the unknown and to appreciate every challenge and every success that came to my way. My special thanks go to my co-supervisor Dr. Yu Mingbin for his patient guidance and valuable comments during my work in IME. I would also like to acknowledge all technical staff in IME and NTU, specifically Mr. M. Fauzi and Ms. Seet Lye Ping in Characterization lab. Many thanks to Dr. Yang Hong for her help in ellipsometry measurements in Republic Polytechnic and to Mr. Sun Yongshun for his friendliness and continuous assistance since the first day I joined NTU. Last but not least, I'd like to thank my dear friend Miss Yasaman Kiasat for her companionship, heartfelt comfort and wise hints all through these years.