“…A fairly general trend in vdW epitaxy. [50] The epitaxy by MBE of bulk PTMCs has been reported without constancy since the 1990s [51][52][53][54][55][56] and unfortunately, most of them reported only the homoepitaxy, or then, the standard heteroepitaxy on GaAs substrates, which results in rough interfaces and growth in other orientations than the [0001], which cannot be directly applied to form the atomic defined interfaces as required for QWs and SLs. Only recently, Sorokin demonstrate the growth of GaTe/ GaSe [49,57] heterostructures that could be used for this goal, however, up to now, no one succeed to grow high-quality InSe/ GaSe heterostructures or to demonstrated quantum confinement on PTMC large-area heterostructures.…”