“…Although to our knowledge this is the first observation of such an effect for strained III-V semiconductor monolayers, similar vacancy ordering has been observed for compressively strained epitaxial Ge monolayers on Si͑001͒. 16 During the deposition of the third monolayer of GaSb on GaAs͑001͒, the growth changes from 2D to 3D as quantum dots appear. Recently, Priester and Lannoo have proposed that the narrow size distribution of such quantum dots is directly related to the presence of a specific type of wetting layer.…”
The growth of GaSb films by molecular beam epitaxy on GaAs͑001͒-c(4ϫ4) at 490°C has been studied in situ with scanning tunneling microscopy and ex situ with transmission electron microscopy. As the film is deposited, four distinct growth regimes are observed: the first two monolayers grow layer by layer with platelet-like two-dimensional ͑2D͒ islands; the next monolayer forms coherently strained three-dimensional ͑3D͒ quantum dots; further deposition induces film relaxation and rough 3D growth; for film thicknesses Ͼ100 nm the growth is again 2D, proceeding via spiral growth around emerging threading dislocations. The atomic-scale mechanisms inherent in the transitions between the growth regimes are discussed. Variations in growth procedures aimed at improving the quantum dot uniformity and reducing the dislocation density are proposed.
“…Although to our knowledge this is the first observation of such an effect for strained III-V semiconductor monolayers, similar vacancy ordering has been observed for compressively strained epitaxial Ge monolayers on Si͑001͒. 16 During the deposition of the third monolayer of GaSb on GaAs͑001͒, the growth changes from 2D to 3D as quantum dots appear. Recently, Priester and Lannoo have proposed that the narrow size distribution of such quantum dots is directly related to the presence of a specific type of wetting layer.…”
The growth of GaSb films by molecular beam epitaxy on GaAs͑001͒-c(4ϫ4) at 490°C has been studied in situ with scanning tunneling microscopy and ex situ with transmission electron microscopy. As the film is deposited, four distinct growth regimes are observed: the first two monolayers grow layer by layer with platelet-like two-dimensional ͑2D͒ islands; the next monolayer forms coherently strained three-dimensional ͑3D͒ quantum dots; further deposition induces film relaxation and rough 3D growth; for film thicknesses Ͼ100 nm the growth is again 2D, proceeding via spiral growth around emerging threading dislocations. The atomic-scale mechanisms inherent in the transitions between the growth regimes are discussed. Variations in growth procedures aimed at improving the quantum dot uniformity and reducing the dislocation density are proposed.
“…In this work, the compressive strain in the alloy was partially transmitted to the substrate and this interaction increases the energy difference between two equivalent configurations of the buckled dimers on the substrate such that it can no longer be suppressed by tip-sample interactions or thermal excitations. It should be pointed out that even though the strain in the 5io.36Geo.64 should be substantially lower than for epitaxial Ge on Si(001) [17], it is still sufficient to buckle the silicon substrate dimers completely.…”
Section: Resultsmentioning
confidence: 99%
“…2b and 2c. This leads to change in the reconstruction from (2 X 1) symmetric to c(4 X 2) antisymmetric (buckled) configuration [17]. Moreover, the dimer structure of the epitaxial alloy is symmetric if the islands are one dimer wide and buckled otherwise [14].…”
We have studied the initial stages of strained SiGe alloy growth on the Si(001)-(2 × 1) surface by scanning tunneling microscopy. The Si0.36Ge0.64 alloy was grown on the silicon substrate at various coverages (0.13-3.6 ML) and at different temperatures (~ 310-470°C). The growth was one dimensional, preferring the direction perpendicular to the underlying silicon dimer rows at low coverages and low temperatures. Anti-phase boundaries were observed to lead multi-layer growth. Strong interaction between the overlayer and the substrate was found to buckle the substrate as well as SiGe dimers. Different growth mechanisms, island formation and step flow, were identified at low and high substrate temperatures. (2 X n) ordering of the strained overlayer was only observed at an intermediate growth temperature (~ 390°C).
“…1 As for group-IV semiconductors, the step interaction on miscut ͑113͒-oriented Si was studied previously, 2,3 but to our knowledge only very few publications concerning the growth of SiGe on Si͑113͒ exist. 4,5 Knall and Pethica 4 have studied the initial growth behavior of low temperature (T growth Ͻ400°C) molecular beam epitaxy ͑MBE͒ of pure Ge on a Si͑113͒ substrate with a very small miscut. Rows of missing atoms parallel to ͓332 ͔ were observed by scanning tunneling microscopy for a Ge coverage of 3 ML, which led to the formation of long ridges with ͕429͖-oriented sidewalls after continued deposition of Ge.…”
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