2023
DOI: 10.1038/s41563-023-01516-1
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Growth of single-crystal black phosphorus and its alloy films through sustained feedstock release

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Cited by 52 publications
(36 citation statements)
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“…To resolve this issue, the group has recently implemented a sustained feedstock release strategy for synthesizing single-crystal black-P thin films, focusing on promoting the lateral growth mode at low nucleation rates. 246…”
Section: Synthetic Strategies Of Elemental Phosphorus Materialsmentioning
confidence: 99%
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“…To resolve this issue, the group has recently implemented a sustained feedstock release strategy for synthesizing single-crystal black-P thin films, focusing on promoting the lateral growth mode at low nucleation rates. 246…”
Section: Synthetic Strategies Of Elemental Phosphorus Materialsmentioning
confidence: 99%
“…The as-grown black-P single-crystal film exhibits outstanding single crystallinity, as evidenced by the full-width at half-maximum of the (040) reflection rocking curve, measured at ∼0.08° using high-resolution XRD. 246 Furthermore, the film has a remarkable carrier mobility of around 6500 cm 2 V −1 s −1 at low temperature. This study marks the first observation of Shubnikov-de Haas oscillations in directly grown black-P films.…”
Section: Synthetic Strategies Of Elemental Phosphorus Materialsmentioning
confidence: 99%
“…), and 2D vdWMs ( e.g. , black phosphorus, 13 MoS 2 , 14,15 WSe 2 , 15 Bi 2 O 2 Se, 16 ReSe 2 , 17 CrTe 2 , 18 Ge 4 Se 9 , 19 ZnIn 2 S 4 , 20 AgInP 2 S 6 , 21 etc. ).…”
Section: Introductionmentioning
confidence: 99%
“…Anisotropic two-dimensional (2D) layered nanomaterials have emerged in the recent years and have attracted extensive attention due to their unique atomic structures and distinguished physical properties, which intrinsically endow the orientation-dependent transport behaviors and numerous potential applications in nanodevices and nanoelectronics. Intriguingly, anisotropic 2D nanomaterials generally possess lattice structures with very low symmetry, much different from the isotropic 2D materials, including the well-studied 6-fold graphene and transitional metal dichalcogenides . As a new degree of freedom, anisotropy in specific 2D materials, such as the orthorhombic black phosphorus (b-P, space group cmce), renders them two principal lattice axes in the basal plane, that is, the orthogonal zigzag (ZZ) and armchair (AC) directions. Till now, many investigations have been performed to explore the anisotropic electrical, phonon vibrational, and thermal properties of 2D b-P. For instance, the anisotropic ratio of thermal conductivity of b-P is determined to be ∼1.8 in the experiment, mainly attributed to the superior phonon velocity and scattering process along the ZZ direction …”
Section: Introductionmentioning
confidence: 99%