1997
DOI: 10.1006/jssc.1997.7319
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Growth of Single Crystals in the Systems withR–Rh–B andR–Rh–B–C (R=Rare Earth Element) from Molten Copper Flux

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Cited by 32 publications
(7 citation statements)
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“…The first such report involved the growth of the series RE Rh 4 B 4 ( RE =Y, Sm, Gd–Tm, and Lu) 294. Later, Japanese workers confirmed these results and reported the additional boride series RE Rh 3 B 2 ( RE =Gd, Dy, Er–Lu) and RE Rh 3 B ( RE =Sm, Gd, Er, Tm) as well as the two boride carbides RE Rh 2 B 2 C with RE =Er and Gd 295a. The layered compound PrRh 4.8 B 2 was obtained as hexagonal plates by a molten metal‐flux growth method, using copper as a flux.…”
Section: Miscellaneous Metallic Fluxes and Materialsmentioning
confidence: 99%
“…The first such report involved the growth of the series RE Rh 4 B 4 ( RE =Y, Sm, Gd–Tm, and Lu) 294. Later, Japanese workers confirmed these results and reported the additional boride series RE Rh 3 B 2 ( RE =Gd, Dy, Er–Lu) and RE Rh 3 B ( RE =Sm, Gd, Er, Tm) as well as the two boride carbides RE Rh 2 B 2 C with RE =Er and Gd 295a. The layered compound PrRh 4.8 B 2 was obtained as hexagonal plates by a molten metal‐flux growth method, using copper as a flux.…”
Section: Miscellaneous Metallic Fluxes and Materialsmentioning
confidence: 99%
“…Erste Berichte betrafen die Kristallzucht der Verbindungen RE Rh 4 B 4 ( RE =Y, Sm, Gd–Tm und Lu) 294. Später wurden diese Ergebnisse von japanischen Forschern bestätigt und durch zwei Reihen von Boriden mit den Zusammensetzungen RE Rh 3 B 2 ( RE =Gd, Dy, Er–Lu) und RE Rh 3 B ( RE =Sm, Gd, Er, Tm) sowie die beiden Boridcarbide RE Rh 2 B 2 C mit RE =Er und Gd erweitert 295a. Die schichtartig aufgebaute Verbindung PrRh 4.8 B 2 wurde in Form hexagonaler Plättchen aus der Kupferschmelze erhalten.…”
Section: Diverse Metallschmelzen Und Materialienunclassified
“…In addition to Al, other metallic fluxes that have been used to grow crystals of metal borides (or borocarbides) include Co, Cu, Zn, Li, Na, Ga, and Sn . More exotic metal eutectics have also been utilized for the crystal growth of metal borides.…”
Section: Resultsmentioning
confidence: 99%