Growth of sodium chlorate crystals in the presence of potassium sulphate

Kim, E.L.; Tsyganova, A. A.; Vorontsov, Dmitry А.; Ovsetsina, T. I.; Katkova, M. R.; Лыков, В. А.; Portnov, V. N.

doi:10.1016/j.jcrysgro.2015.06.016

Cited by 1 publication

(2 citation statements)

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“…It is possible that this is the reason why sometimes different authors do not draw the same conclusions about the growth mechanism for the same substances and experimental conditions. Nonequivalent crystal faces can grow by different mechanisms, especially in the presence of impurities. , …”

Section: Discussionmentioning

confidence: 99%

“…Nonequivalent crystal faces can grow by different mechanisms, especially in the presence of impurities. 10,49 It is more difficult to determine the function which describes growth rate versus supersaturation dependence from crystal growth in the ⟨100⟩ direction than from growth of {100} faces. This can be seen from Figure 7 which shows growth rate in ⟨100⟩ direction versus supersaturation dependence before dissolution.…”

Section: ■ Discussionmentioning

confidence: 99%

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Investigation of Growth Mechanisms of Sodium Chlorate Crystals from Aqueous Solutions

Radiša

Mitrovic

Misailović

et al. 2016

Ind. Eng. Chem. Res.

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Difficulties in determining the crystal growth mechanism from growth rate versus solution supersaturation dependence are discussed. Obtained results indicate that in the supersaturation range of 0.66−1.56%, sodium chlorate crystals grow in accordance with the spiral growth model. It is shown that in the supersaturation range of 0.44−1.32%, the growth mechanism depends on crystal growth history. Namely, the exponent n in the power law R = Kσ n depends on the manner of supersaturation changes (varied from 1.3 to 1.9%). This indicates that the overlapping of diffusion fields of neighboring steps depends on growth history.

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Section: Discussionmentioning

confidence: 99%

Section: ■ Discussionmentioning

confidence: 99%