SummaryThe issues of cluster synchronization and state estimation for a class of nonlinear complex dynamical networks are concurrently focused in this study. In precise, led by the design of complex dynamical networks, a proportional integral‐based observer is implemented for achieving robustness, by the virtue of which the states of examined networks are estimated. Thereupon, a proportional integral observer‐based hybrid triggered control scheme is proposed, wherein, the switch‐over between time‐ and event‐ triggered scheme is governed through a Bernoulli distributed random variable. Further, with the application of mixed and passivity performance technique, the external disturbances for the addressed complex dynamical networks are reduced. Based on the Lyapunov stability theory, the requisite sufficient conditions in respect of linear matrix inequalities are provided which ensures the discussed complex dynamical network's synchronization phenomenon. In a further, the presented criteria are exploited for the attainment of required controller, proportional and integral gain matrices. In conclusion, the applicability of proposed results and efficacy of the undertaken strategy are evidently proven with the illustration of two numerical examples with Chua's circuit and Goodwin oscillator model.