2024
DOI: 10.1002/ange.202319552
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Guest‐Facilitated Heteroleptic Assembly of Helical Anionocages Enables Reversible Chirality Modulation

Shanshan Wang,
Xuanli Ye,
Zaiwen Yang
et al.

Abstract: We report a novel strategy for reversible modulation of supramolecular chirality, based on guest‐facilitated heteroleptic assembly of helical anionocages. Two triple‐stranded helical anionocages, including a chiral cage 1 (A2L13) and a crown ether functionalized, achiral cage 2 (A2L23) were synthesized by anion coordination of bis‐monourea‐based ligands and PhPO32‐. Both cages exhibited favorable binding with tetraethylammonium TEA+ and cobaltocenium Cob+ (endo‐guest, bound in the cavity). Additionally, cage 2… Show more

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