This research is focused on the problem of agile attitude maneuvering, aimed at the precise pointing of a satellite forming a typical constellation in low Earth orbit. We consider two different operational scenarios: (a) pointing toward a specific ground station, located on the Earth surface (for downlink data routing), and (b) pointing toward a companion satellite (for establishing an intersatellite connection). The two preceding operational requirements can both be formulated as attitude tracking problems. In this study, we use an inertia-free nonlinear attitude control algorithm based on rotation matrices and possessing remarkable stability properties, in conjunction with a pyramidal array of single-gimbal control momentum gyroscopes. Numerical simulations, in both nominal and nonnominal flight conditions, demonstrate that the attitude control architecture proposed in this work is effective for the purpose of performing agile attitude maneuvering, aimed at precise pointing during downlink and intersat data routing.