Understanding the pore heterogeneity of tectonic coal
and primary-structure
coal is of great significance for predicting and preventing tectonic
coal. This study adopts the low-temperature nitrogen adsorption method,
mercury injection experiment, and other methods, combined with fractal
theory, to quantitatively analyze the pore distribution of coal samples
inside and outside the outburst cavities of the Sanjia coal mine.
The experiments have shown that the contents of aliphatic functional
groups and hydrogen in tectonic coal are higher than those of aromatic
structural functional groups. Raw coal has more straight chains than
side chains, whereas aliphatic hydrocarbon mostly has short chains,
and the branching degree is high. Soft and primary-structure coals
have similar elemental content and tectonic effects endow the coal
with better connectivity. The pores are filled with particles and
flakes, and the surfaces of tectonic coal have more pores and fissures
on them. According to the experimental curve, the pores are divided
into five types. The pore size of primary-structure coal is mainly
type II pores, and the pore size distribution of tectonic coal is
relatively wide, with the majority being class I and class II pores.
The specific surface area of tectonic coal is 60.7% more than that
of primary-structure coal. The box fractal dimension of coal decreases
with the increase in scanning electron microscopy (SEM) magnification.
The minimum fractal dimension of tectonic coal is 2.49, which is 7.8%
lower than the peak of 2.70. It can be seen from the fractal dimension
that the fractal dimensions of pore types II, III, and IV are rougher.