h‐BN huddled starch reinforced polyethylhexylacrylate\polyvinyl alcohol thin films for packaging applications

Prusty, Kalyani; Swain, Sarat K.

doi:10.1002/pc.24941

Cited by 8 publications

(3 citation statements)

References 55 publications

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“…This result clearly evidenced that CNC was able to promote the crystallization of the matrix, acting as heterogeneous nucleating agents. [45] The diffraction peaks of USP films at 11.755°and 19.678°were observed in Table 2, and the interplanar distance was 0.7522 and 0.4507 nm, respectively. Compared with the SP film, the 2𝜃 angle changed slightly.…”

Section: Xrd Analysis Of Sp-based Filmsmentioning

confidence: 97%

Hydrogen Bonding Crosslinking of Starch‐Polyvinyl Alcohol Films Reinforced by Ultrasound‐Assisted and Cellulose Nanofibers Dispersed Cellulose Nanocrystals

Jia

Teng²,

Huang³

et al. 2022

Starch Stärke

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The study reports the effects of cellulose nanofibers (CNF) and an ultrasound-assisted method dispersed cellulose nanocrystals (CNC) on the mechanical and water resistance properties of starch-polyvinyl alcohol (PVA) films. Starch-PVA (SP) based films are prepared by casting method, compared with the original SP films, the ultrasound-assisted and CNF are beneficial to the dispersion of CNC in nanocomposites, and the tensile strength (TS) of the ultrasound treatment starch/PVA/CNC/CNF (USPCF) film is increased to 10.63 MPa, an increase by 60%. The cross-section morphology of the USPCF film is smoother and more homogeneous, indicating the particle size of CNC is small. The structure of blend films is homogeneous and compact due to the CNC full playing to the nano-effect, which is the main reason for the improvement of SP-based films in mechanical properties. Fourier Transform Infrared spectroscopy shows the hydrogen bonding is formed between SP and the fillers, while X-ray diffraction shows that the crystallinity of nanocomposite films is decreased with ultrasonication. From the results, it can be concluded that CNF and ultrasound-assisted dispersed nanoparticles could reinforce the SP-based films efficiently to prepare green nanocomposite films.

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Section: Xrd Analysis Of Sp-based Filmsmentioning

confidence: 97%

Hydrogen Bonding Crosslinking of Starch‐Polyvinyl Alcohol Films Reinforced by Ultrasound‐Assisted and Cellulose Nanofibers Dispersed Cellulose Nanocrystals

Jia

Teng²,

Huang³

et al. 2022

Starch Stärke

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“…Prusty et al prepared BN‐based PEHA/PVA‐s@h‐BN polymer composite film for packaging applications. [ 52 ] Mahadeva et al [ 53 ] used a solution blending procedure to produce SnO 2 nanoparticle‐laden cellulose hybrid thin films. The hybrid thin films are investigated for biodegradable humidity sensors in terms of the material's change in electrical resistivity when exposed to a wide range of humidity.…”

Section: Introductionmentioning

confidence: 99%

Synergistic effect of hybrid hydroxylated boron nitride and cellulose nanocrystals for enhancing the thermal, mechanical, and hydrophobic properties of composite film

et al. 2022

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Hybrid composite films are largely preferred over neat films because of their superior thermal, mechanical, chemical, and hydrophobic properties. The hybrid composite film has a wide range of use, including space, defense, electronics, packaging, and engineering applications. Fabricating multifunctional hybrid composite films with biodegradable polymer and biodegradable filler such as cellulose nanocrystals has become popular in recent years as an alternative to conventional plastics. In this paper, hybrid hydroxylated boron nitride (BN) nanoparticles with CNC nano‐filer reinforced composite PVA films were fabricated. The obtained composite films were characterized for morphological, chemical, physical, thermal, and hydrophobic properties. The morphological analysis indicates that the hybrid nano‐filler was well dispersed in the poly(vinyl alcohol) (PVA) matrix. The reaction and hydrogen bond interactions between CNC and BN in composite films are confirmed by the Fourier transform infrared spectroscopy and x‐ray diffraction pattern. The contact angle method is used to confirm the enhancement of the hydrophobic property. The physical properties of the composite films and neat PVA film were analyzed by tensile test method using a universal testing machine. The thermal stability of the neat PVA film and the composite films were analyzed by the thermo‐gravimetric analysis method. The effect of hybridization of nanoparticles on the thermal, mechanical, and hydrophobic properties was studied. The hybrid composite film with enhanced properties allows it for multifunctional applications.

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“…Hexagonal boron nitride, which is considered as a structural analogue of graphene [ 12 ], has received an enormous amount of attention in the last few years [ 13 , 14 ], due to its versatile features: excellent thermal and mechanical properties, chemical stability [ 15 ], low density [ 16 ], and biocompatibility [ 17 ], to name few. The latter along with unique mechanical strength allow its application in composite materials [ 18 ] to enhance their properties, especially for the paper-making industry.…”

Section: Introductionmentioning

confidence: 99%

Few Layered Oxidized h-BN as Nanofiller of Cellulose-Based Paper with Superior Antibacterial Response and Enhanced Mechanical/Thermal Performance

Onyszko

Markowska‐Szczupak

Rakoczy

et al. 2020

IJMS

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In this study, hexagonal boron nitride nanosheets enriched with hydroxyl groups (h-BN-OH) were successfully grafted on the surface of cellulose fibers after the simple and effective exfoliation and oxidation of bulk h-BN. OH groups of h-BN-OH and the ones presented on the surface of cellulose fibers interacted via hydrogen bonding. Both spectroscopic (FT-IR, XRD) and microscopic (TEM, SEM, and atomic force microscopy (AFM)) methods results proved the successful functionalization of the cellulose fibers with the nanomaterial. Modified cellulose fibers were used to prepare paper sheets samples with different concentrations of the nanomaterial (1 wt %, 2 wt %, and 3 wt %). All the samples were tested for the antibacterial properties via the colony forming unit method and exhibited good performance against both Gram-negative (E. coli) and Gram-positive (S. epidermidis) model bacteria. Additionally, the influence of the volume of working bacterial suspension on the antibacterial efficiency of the obtained materials was examined. The results showed significantly better antibacterial performance when the volume of bacterial suspension was reduced. Mechanical properties of the paper samples with and without nanofiller were also characterized. Tensile strength, tearing strength, and bursting strength of the paper samples containing only 2 wt % of the nanofiller were improved by 60%, 61%, and 118% in comparison to the control paper samples, respectively. Furthermore, the nanofiller improved the thermal properties of the composite paper—the heat release rate decreased by up to 11.6%. Therefore, the composite paper can be further explored in a wide range of antibacterial materials, such as packaging or paper coatings

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h‐BN huddled starch reinforced polyethylhexylacrylate\polyvinyl alcohol thin films for packaging applications

Cited by 8 publications

References 55 publications

Hydrogen Bonding Crosslinking of Starch‐Polyvinyl Alcohol Films Reinforced by Ultrasound‐Assisted and Cellulose Nanofibers Dispersed Cellulose Nanocrystals

Hydrogen Bonding Crosslinking of Starch‐Polyvinyl Alcohol Films Reinforced by Ultrasound‐Assisted and Cellulose Nanofibers Dispersed Cellulose Nanocrystals

Synergistic effect of hybrid hydroxylated boron nitride and cellulose nanocrystals for enhancing the thermal, mechanical, and hydrophobic properties of composite film

Few Layered Oxidized h-BN as Nanofiller of Cellulose-Based Paper with Superior Antibacterial Response and Enhanced Mechanical/Thermal Performance

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