H-bonded system of 1-D d and π states; [Pd(H2EDAG)(HEDAG)]TCNQ

[structure: see text] A novel TTF-based donor with a uracil moiety, TTF-(1-n-butyluracil-5-yl) (TnbU), was synthesized. Crystal structures of both TnbU and the charge-transfer complex of TnbU-hydrogen cyananilate possess complementary double hydrogen bonds through uracil moieties and pi-stacking dimer structures between TTF skeletons. Furthermore, the TnbU-TCNQ charge-transfer complex shows a high electrical conductivity underlying the partial charge-transfer accompanied by a hydrogen-bonding interaction, which was substantiated in terms of the measurements of the IR, electronic spectra, and conductivity.

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H-bonded system of 1-D d and π states; [Pd(H2EDAG)(HEDAG)]TCNQ

Cited by 8 publications

References 3 publications

Hydrogen-bonded networks of 2,2′-substituted 4,4′-biimidazoles: New ligands for the assembled metal complexes

Hydrogen-bonded networks of 2,2′-substituted 4,4′-biimidazoles: New ligands for the assembled metal complexes

Filling control of the 1-D band of TCNQ in H-bonded organic-inorganic hybrid system

Hydrogen-Bonded Charge-Transfer Complexes of TTF Containing a Uracil Moiety: Crystal Structures and Electronic Properties of the Hydrogen Cyananilate and TCNQ Complexes

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