H/D Exchange of Aromatic Sulfones via Base Promotion and Silver Catalysis

Xu, Hui; Jiang, Zhi-Jiang; Jia, Yun; Su, Yuhang; Bai, Jian-Fei; Gao, Zhanghua; Chen, Jia; Gao, Kun

doi:10.1021/acs.joc.4c00352

J. Org. Chem.

2024

DOI: 10.1021/acs.joc.4c00352

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H/D Exchange of Aromatic Sulfones via Base Promotion and Silver Catalysis

Hui Xu,

Zhi-Jiang Jiang,

Yun Jia

et al.

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Cited by 2 publications

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Mechanochemically facilitated silver-catalyzed direct H/D exchange on heteroarenes

Jia,

Jiang,

Han

et al. 2025

Org. Biomol. Chem.

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Mechanochemically facilitated silver-catalyzed direct H/D exchange on heteroarenes

Jia,

Jiang,

Han

et al. 2025

Org. Biomol. Chem.

View full text Add to dashboard Cite

show abstract

Transition-Metal-Catalyzed Deuteration via Hydrogen Isotope Exchange

Jiang,

Gao,

Bai

2024

SynOpen

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Direct hydrogen isotope exchange represents a distinctive strategy for deuterium labelling, where the protium is directly replaced by deuterium. In this graphic review, we summarized the progress in deuteration via transition metal catalyzed hydrogen isotope exchange. The review was organized according to the mechanism of C-H bond activation in the homogeneous catalysis, and the heterogeneous catalysis was also discussed according to the catalyst type. Representative mechanistic processes were depicted, and proven cases for tritiation were also highlighted.

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H/D Exchange of Aromatic Sulfones via Base Promotion and Silver Catalysis

Cited by 2 publications

References 46 publications

Mechanochemically facilitated silver-catalyzed direct H/D exchange on heteroarenes

Mechanochemically facilitated silver-catalyzed direct H/D exchange on heteroarenes

Transition-Metal-Catalyzed Deuteration via Hydrogen Isotope Exchange

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