The authors have proposed the use of a hydrogen concentration probe as a new simple method of evaluating hydrogen concentration. We propose a method of evaluating the rate of change of catalytic heat release in order to evaluate hydrogen concentration history for the condition under which the boundary layer is likely to be immature. By using a shock tube, the rate of increase of heat budget of platinum wire was investigated experimentally. Experimental results indicate that the rate of increase of difference due to catalytic heat release is the maximum value when the hydrogen concentration is 30%, which agrees well with a previous result. As a result, this method can be used to evaluate the rate of increase of difference due to catalytic heat release. It is clear that the rate of change due to catalytic heat release is strongly correlated with the rate of change of hydrogen concentration.