This paper describes the implementation and performance of CsI(Tl) pulse shape discrimination for the Belle II electromagnetic calorimeter, representing the first application of CsI(Tl) pulse shape discrimination for particle identification at an electron-position collider. The pulse shape characterization algorithms applied by the Belle II calorimeter are described. Control samples of γ, µ + , π ± , K ± and p/p are used to demonstrate the significant