2017
DOI: 10.1016/j.jorganchem.2016.11.014
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Half-sandwich rhodium and iridium fragments and carboxylate ligands as building blocks for the formation of metallamacrocycles

Abstract: A series of half-sandwich rhodium and iridium complexes containing carboxylate ligands were synthesized and characterized. Reactions between [Cp*MCl 2 ] 2 (M = Ir or Rh) and 1,3,6bis(2-pyridyl)-1,2,4,5-tetrazine (L1) gave binuclear complexes 1 and 2 under different conditions. The half-sandwich iridium and rhodium metallamacrocycles complexes 3-5 were constructed in a stepwise manner by the addition of carboxylate ligands (sodium acetate or the conjugate bases of pyrazine-2,3-dicarboxylic acid or 3-(2-pyridyl)… Show more

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Cited by 8 publications
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