This is the first of two papers on quasi-split affine quantum symmetric pairs U( g), U ı , focusing on the real rank one case, i.e., g = sl 3 equipped with a diagram involution. We construct explicitly a relative braid group action of type A(2) 2 on the affine ıquantum group U ı . Real and imaginary root vectors for U ı are constructed, and a Drinfeld type presentation of U ı is then established. This provides a new basic ingredient for the Drinfeld type presentation of higher rank quasi-split affine ıquantum groups in the sequel. Contents 1. Introduction 1 2. Relative braid group action 6 3. Proof of Theorem 2.7 11 4. Constructions of root vectors 14 5. A Drinfeld type presentation 18 6. Verification of the current relations 22 Appendix A. Proofs of Identity (3.8) and Lemma 6.2 34 References 41 2010 Mathematics Subject Classification. Primary 17B37.