Halogenation triggering rules in hybrid materials for fluorescence and dielectric phase transitions

Abstract

Organic-inorganic hybrid materials with controllable physicochemical properties have played a great role in multifunctional sensors, photovoltaic cells, switching devices, etc. Among them, organic-inorganic hybrid dielectric materials have become a research...

Dehydration Induced a Structural Transformation into a One-Dimensional Hybrid Perovskite with Second Harmonic Generation and Dual Dielectric Switching

“…Overall, the blue-light emission of compound 2 may be attributed to the synergistic effect of the confinement of the exciton in the [CdCl 3 ] − inorganic chains and organic salt [C 5 NOH 12 ]­Cl, which drives the slight difference compared with compound 1 . Additionally, the time-resolved PL decay of compounds 1 and 2 is modeled using double-exponential functions with average lifetimes of 0.73 and 1.42 ns (Figure e,f), respectively, which are comparable to those reported for 1D organic–inorganic hybrid perovskites in previously studies . The intriguing photoluminescence properties make compounds 1 and 2 potential candidate materials in the field of solid-state optics.…”

Structural phase transition and dielectric responses in two novel cyano-bridged coordination polymers synthesized by sealing the incomplete cyano-bridged cage

“…[5][6][7] Compared with traditional pure organic/inorganic materials, organic-inorganic hybrid materials have greater potential to change the internal molecular arrangement and act as a temperature responsive phase transition material. [8][9][10][11][12][13][14] Taking three-dimensional organic-inorganic hybrid perovskites, for example, guest cations were imprisoned in the cagedlike anionic host framework and could undergo a phase transition from the order/static state to the disorder/dynamic state upon a thermal stimulus. [15][16][17] This classical model of the cationic guest in a three-dimensional anion skeleton is an ideal and hypothetical design precept for phase change materials.…”

“…5–7 Compared with traditional pure organic/inorganic materials, organic–inorganic hybrid materials have greater potential to change the internal molecular arrangement and act as a temperature responsive phase transition material. 8–14…”

Molecular orientation dynamics triggers ferroelectricity and ferroelasticity in an organic–inorganic halide material

“…10 Admittedly, the close connection between molecular dynamics and symmetry breaking is responsible for the diversity of physical properties, beautiful appearance, and the complexity of the design. 11–17 Therefore, exploring the dynamics of molecular orientation is a critical and difficult step in understanding and designing ferroic materials.…”