This study aims to discuss the load intensity monitoring in the training process of sitting volleyball, to help coaches understand the training status of athletes, and to provide a scientific basis for the follow-up training plan. Through big data technology, the physiological changes of athletes can be more accurately grasped. This includes classification and summary of exercise load intensity and experimental study of the relationship between heart rate and rating perceived exertion (RPE). Through monitoring the training process of a provincial women’s sitting volleyball team, it is found that there is a significant positive correlation between athletes’ RPE and average heart rate. This result shows that by monitoring the change in heart rate and RPE of athletes, athletes' training state and physical condition can be more accurately understood. The results reveal that through the use of big data technology and monitoring experiments, it is found that heart rate and RPE are effective monitoring indicators, which can scientifically reflect the load intensity during sitting volleyball training. The conclusions provide coaches with a more scientific basis for making training plans and useful references for sports involving people with disabilities.