Hardening of Mortars from Blended Cement with Opoka Additive in CO2 Environment

Abstract

The influence of the parameters of accelerated carbonization in a 99.9% CO2 environment on the hardening kinetics of blended cement with 15 wt% opoka additive, the physical and mechanical properties of the resulting products, the mineralogical composition, and the amount of absorbed CO2 were investigated. Sedimentary rock opoka was found to have opal silica and calcite as its predominant constituent parts. Therefore, these properties determine that it serves as an extremely suitable raw material and a source of both SiO2 and CaO. The strength properties of the mortars (blended cement/standard sand = 1:3) were similar or even better than those of samples based on Ordinary Portland cement (OPC): the compressive strength exceeded 50 MPa under optimal conditions. In blended cement, some of the pores are filled with fine-dispersed opoka, which can lead to an increase in strength. By reducing the amount of OPC in mixtures, the negative impact of its production on the environment is reduced accordingly. Using XRD, DSC, and TG methods, it was determined that replacing 15 wt% of OPC clinker with opoka does not affect the mineralogy of the crystalline phases as the same compounds are obtained. After determining the optimal parameters for sample preparation and hardening, in accordance with the obtained numbers, concrete pavers of industrial dimensions (100 × 100 × 50 mm) were produced. Their strength indicators were even ~10% better.