“…2,3 Due to the complex impurities, such as phosphorus, fluorine, residual acid, organic matter, and even heavy metals, it is difficult to recycle it. [4][5][6][7] Especially, the harmful substances existing in the gypsum crystals will be slowly released during the dissolution process, 8,9 seriously affecting the application value of materials. 10 At present, the preparation of α-hemihydrate gypsum (α-HH) from PG has been widely recognized in the field of building materials, α-HH has good workability, and related products have excellent performance in strength, hardness, biocompatibility, and other aspects, with obvious advantages of high value-added.…”