Headspace-Solid-Phase Microextraction in the Analysis of the Volatile Fraction of Aromatic and Medicinal Plants

Belliardo, Flavio; Bicchi, Carlo; Cordero, Chiara Emilia Irma; Liberto, Erica; Rubiolo, Patrizia; Sgorbini, Barbara

doi:10.1093/chromsci/44.7.416

Cited by 79 publications

(35 citation statements)

References 92 publications

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“…Among the analytical techniques currently available for extracting and quantifying volatile compounds in samples, headspace solid-phase micro-extraction (HS-MPSE), has been widely used to analyze volatile compounds in foods and beverages because its simplicity, versatility, flexibility, efficient sample preparation, and sensitive detection (Belliardo et al, 2006). HS-SPME with Divinyl benzene/Carboxen/Polydimethylsiloxane (DVB/CAR/PCMS) fibers has been used to monitor the evolution of volatiles directly during storage (Bryant & McClung, 2011;Laguerre, Mestres, Davrieux, Ringuet, & Boulanger, 2007;Zeng, Zhang, Chen, Zhang, & Matsunaga, 2008).…”

Section: Introductionmentioning

confidence: 99%

Effect of selenium enrichment on the quality of germinated brown rice during storage

Liu

Chen

2016

Food Chemistry

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Section: Introductionmentioning

confidence: 99%

Effect of selenium enrichment on the quality of germinated brown rice during storage

Liu

Chen

2016

Food Chemistry

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“…Headspace solid-phase micro-extraction (HS-SPME) is a rapid and simple procedure successfully used to sample the volatile components of aromatic and medicinal plants. [20][21][22][23][24] HS-SPME analysis allowed the fingerprint of the plant headspace to be rapidly obtained. HS sampling needs the optimization of extraction parameters.…”

Section: Introductionmentioning

confidence: 99%

“…Concerning times and temperatures of equilibrium and extraction, various conditions have been reported, according to the plant material. [20][21][22][23][24] In the present study, the temperature and extraction times used for the HS analysis were optimized.…”

Section: Introductionmentioning

confidence: 99%

Qualitative and quantitative analysis of volatile components of Teucrium massiliense L. – identification of 6‐methyl‐3‐heptyl acetate as a new natural product

Djabou¹,

Paolini²,

Desjobert³

et al. 2010

Flavour & Fragrance J

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Volatile components extracted from the aerial parts and separated organs of Corsican and Sardinian Teucrium massiliense have been studied. The chemical composition of essential oils obtained by hydrodistillation (HD) has been investigated using GC-RI, GC-MS (EI and CI modes) and 13 CNMR spectroscopy. For the first time, a real concentration via calibration curves and response factor calculations has been determined for each oil component. The concentrations of the major components were 6-methyl-3-heptyl acetate (23.83-18.16 g/100 g), 3-octyl acetate (10.55-6.95 g/100 g), isobutyl isovalerate (7.67-2.91 g/100 g), germacrene D (6.13-1.01 g/100 g) and linalool (6.63-5.23 g/100 g). To the best of our knowledge, the occurrence of 6-methyl-3-heptyl acetate as a natural product is reported for the first time. Furthermore, the chemical composition of volatile fractions emitted from the aerial parts and separated organs of T. massiliense L. has been studied by HS-SPME/ GC-RI and GC-MS after optimization of SPME parameters. Concerning the contribution of plant organs to the aromatic plant fingerprint, we noted that the flowers produced more volatiles than other organs. The volatile fractions obtained from the different organs were qualitatively quite similar to each other but differed in the percentages of their major components. Also, the influence of HS-SPME extraction parameters (equilibrium and extraction times and temperature) on the chemical composition of the plant volatile fraction is discussed.

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“…This article aims to evaluate the recovery repeatability and intermediate precision of two sets of fibres belonging to different lots and coated with two different coatings (i.e six 100 m polydimethylsyloxane (PDMS) and three Carboxen/ polydivinylbenzene/polydimethylsyloxane 50/30 m, l: 1 cm (CAR/DVB/PDMS)) and their performance over time when applied to HS-SPME sampling for the quality control of medicinal and aromatic plants [9], in particular chamomile (Matricaria chamomilla L.) and sage (Salvia lavandulifolia Vahl.) and of a standard solution containing four compounds with different structures, polarity and volatility (i.e.…”

Section: Introductionmentioning

confidence: 99%

Reliability of fibres in solid-phase microextraction for routine analysis of the headspace of aromatic and medicinal plants

Bicchi

Cordero

Liberto

et al. 2007

Journal of Chromatography A

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This article evaluates the HS-SPME recovery repeatability, intermediate precision and their performance over time when applied to HS-SPME sampling for quality control of medicinal and aromatic plants. Experiments were carried out on two sets of fibres coated with two different coatings and belonging to different lots (i.e 100 m polydimethylsyloxane (PDMS) and Carboxen/divinylbenzene/PDMS 50/30 m, l: 1 cm (CAR/DVB/PDMS)) and on chamomile (Matricaria chamomilla L.), sage (Salvia lavandulifolia Vahl.) and a standard solution containing 3-hexanol, isoamyl acetate, 1,8-cineole and menthol in diisobutyl phthalate. The performance of each set of fibres was evaluated by determining a group of complementary statistical parameters including: (i) repeatability of the absolute areas of each marker from each matrix with each fibre; (ii) intra-fibre repeatability of the total absolute areas of the markers of each matrix obtained with each fibre of each set; (iii) inter-fibre intermediate precision of the total absolute areas of the markers of each matrix obtained with all fibres of each set; and (iv) analysis of variance by one-way ANOVA with Fisher and Tukey tests. The influence of the number of analyses on fibre effectiveness (fibre life-time) was studied by linear regression analysis (LRA). The results proved that HS-SPME can successfully be used for routine control analysis of aromatic ad medicinal plants since both types of fibres showed good repeatability and intermediate precision of analytes recovery and consistency over time. Unlike data previously reported by other authors, CAR/DVB/PDMS coated fibres gave better results than those coated with PDMS. The fibre-life seemed mainly to be influenced by the number and conditions of samplings and nature of the matrix investigated.

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Headspace-Solid-Phase Microextraction in the Analysis of the Volatile Fraction of Aromatic and Medicinal Plants

Cited by 79 publications

References 92 publications

Effect of selenium enrichment on the quality of germinated brown rice during storage

Effect of selenium enrichment on the quality of germinated brown rice during storage

Qualitative and quantitative analysis of volatile components of Teucrium massiliense L. – identification of 6‐methyl‐3‐heptyl acetate as a new natural product

Reliability of fibres in solid-phase microextraction for routine analysis of the headspace of aromatic and medicinal plants

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