Atmospheric
nitrous acid (HONO) is a dominant precursor of hydroxyl
(OH) radicals, and its formation mechanisms are still controversial.
Few studies have simultaneously explored effects of different combustion
processes on HONO sources. Hereby, synchronous HONO measurement in
urban (BJ), suburban (XH) and rural (DBT) areas with different combustion
processes is performed in the North China Plain in winter. A box
model is utilized to analyze HONO formation mechanisms. HONO concentration
is the highest at the DBT site (2.51 ± 1.90 ppb), followed by
the XH (2.18 ± 1.95 ppb) and BJ (1.17 ± 1.20 ppb) sites.
Vehicle exhaust and coal combustion significantly contribute to nocturnal
HONO at urban and rural sites, respectively. During a stagnant pollution
period, the NO+OH reaction and combustion emissions are more crucial
to HONO in urban and rural areas; meanwhile, the heterogeneous reaction
of NO2 is more significant in suburban areas. Moreover,
the production rate of OH from HONO photolysis is about 2 orders of
magnitude higher than that from ozone photolysis. Consequently, vehicle
exhaust and coal combustion can effectively emit HONO, further causing
environmental pollution and health risks. It is necessary to expand
the implementation of the clean energy transition policy in China,
especially in areas with substantial coal combustion.