ABSTRACT:The paper investigated the heavy metal ions adsorption by bio-adsorbent obtained from modifying bagasse pith. The bagasse pith, a main solid bio-waste from sugar and pulp industry, was treated by epichlorohydrin and diethylenetriamine. The pith before and after modification were analyzed to characterize its structure change by Fourier Transform Infrared Spectroscopy and Scanning Electron Microscope. It shown that numbers of minor fragments cohere to the surface of fibrous bundle of modified pith. The carboxyl groups has been introduced with the change of substitutional groups in aromatic skeletal of lignin on surface of pith. The kinetics and thermo-dynamic properties were studied. The results shown the adsorption process are well described by Langmuir isotherm and pseudo-2nd order model. It is considered that the bagasse pith, a renewable bio-waste, would be modified to treat the waste water polluted by heavy metal in further studies.