With growing energy demands and the looming depletion of fossil fuels, electrochemical energy conversion and storage systems are under aggressive development for current and future renewable energy needs [1]. Hybrid electric vehicles (HEVs), combining two power sources-internal combustion engines and electric motors in order to achieve better performance, are already common. The major types of electrochemical storage system are batteries, capacitors, fuel cells, and their combinations. The prime performance metrics for comparing these technologies are reliability, power and energy density, cycle-life, temperature range and emission of pollutants. Batteries and capacitors are closed systems with anodes, cathodes and separators that are soaked with electrolytes and sealed in a single compartment. Conversely in fuel cells, the fuel, consisting of hydrogen at the anode and oxygen at the cathode, is supplied from a tank. Figure 1.1 provides a Ragone plot that compares different electrochemical energy storage systems to internal combustion engines and turbines, and electrolytic capacitors. As apparent from the simplified Ragone plot, supercapacitors bridge the gap between conventional electrolytic capacitors and batteries in terms of specific energy and power densities. The terms specific energy (in Wh kg −1 ) and energy density in (Wh L −1 ) are generally used to assess energy storage systems, whereas their rate capability is represented by specific power (in W kg −1 ) or power density (in W L −1 ). Thermal management of energy storage systems is essential for their high performance over suitably wide temperature ranges. At low temperatures, performance decays mainly because of the low ionic conductivity of the electrolyte; while at high temperatures, the components tend to age due to a series of side reactions, causing safety and reliability issues [2]. Therefore, trade-offs exist among system performance, functionality, design, cost, maintenance, and safety. Optimization of these parameters to achieve high performance of power supplies requires fundamental and thorough understanding of thermal transport in the systems. This chapter provides a brief introduction to thermal management in major electrochemical energy storage systems.