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Heat resistance, as well as friction and wear of composite coatings Cr–Si–B–MgC2 under conditions of elevated temperatures implemented in friction pairs, were investigated. The selection of the Cr–Si–B–MgC2 composition and its optimal composition for spraying wear-resistant coatings loaded with friction at high temperatures are substantiated. Indicated the main influence on the properties, structure, and stability of heterogeneous coatings is exerted by alloying elements at certain concentrations, as well as technological parameters of coating application. It has been established that silicon and boron contribute to the formation of complex-alloyed high-temperature formations with increased wear resistance. The microhardness of coatings correction is realized due to the silicon percentage content, while the mechanical properties of the material are increased by additional doping with boron and magnesium carbide. The parameters of sputtering of coatings are also important, on which the formation of a heat-resistant layer directly depends. It was experimentally established that the ratio of consumption of acetylene and oxygen ~20/25 l/min ensures the stability of technological parameters of sputtering, homogeneity of the chemical composition and constancy of coating properties. At a load of up to 5.0 MPa, a sliding speed of up to 1.2 m/s and a temperature of up to 700С, the coatings of the Cr–Si–B–MgC2 system show stable structural adaptability, which ensures the minimization of friction and wear parameters. Metallographic analysis and profilography of the samples indicate that there are no visible damages on the friction surfaces, and individual sticking points are localized in thin film surface layers. It was established that the dependence of the microhardness of the surface structures on the temperature is monotonic, but jumps are also observed if polymorphic transformations or transformations of metastable states into more stable and stable ones during heating and cooling occur. Microhardness indicators are uniform because particles of inclusions and impurities are dissolved in the oxide structures, which significantly affect the microhardness, and therefore, the properties of oxides of both simple and complex compositions. Keywords: protective coatings, surface layer, resistance to oxidation, wear resistance, heat resistance
Heat resistance, as well as friction and wear of composite coatings Cr–Si–B–MgC2 under conditions of elevated temperatures implemented in friction pairs, were investigated. The selection of the Cr–Si–B–MgC2 composition and its optimal composition for spraying wear-resistant coatings loaded with friction at high temperatures are substantiated. Indicated the main influence on the properties, structure, and stability of heterogeneous coatings is exerted by alloying elements at certain concentrations, as well as technological parameters of coating application. It has been established that silicon and boron contribute to the formation of complex-alloyed high-temperature formations with increased wear resistance. The microhardness of coatings correction is realized due to the silicon percentage content, while the mechanical properties of the material are increased by additional doping with boron and magnesium carbide. The parameters of sputtering of coatings are also important, on which the formation of a heat-resistant layer directly depends. It was experimentally established that the ratio of consumption of acetylene and oxygen ~20/25 l/min ensures the stability of technological parameters of sputtering, homogeneity of the chemical composition and constancy of coating properties. At a load of up to 5.0 MPa, a sliding speed of up to 1.2 m/s and a temperature of up to 700С, the coatings of the Cr–Si–B–MgC2 system show stable structural adaptability, which ensures the minimization of friction and wear parameters. Metallographic analysis and profilography of the samples indicate that there are no visible damages on the friction surfaces, and individual sticking points are localized in thin film surface layers. It was established that the dependence of the microhardness of the surface structures on the temperature is monotonic, but jumps are also observed if polymorphic transformations or transformations of metastable states into more stable and stable ones during heating and cooling occur. Microhardness indicators are uniform because particles of inclusions and impurities are dissolved in the oxide structures, which significantly affect the microhardness, and therefore, the properties of oxides of both simple and complex compositions. Keywords: protective coatings, surface layer, resistance to oxidation, wear resistance, heat resistance
The investigation results of friction and wear of the developed detonation composite coatings FeAl2-Ti-Si-B under high-temperature friction conditions are presented. The choice of FeAl2-Ti-Si-B composition and its optimal content for spraying wear-resistant coatings loaded with friction under high-temperature conditions are justified. It is noted that the alloying elements at definite concentrations and technological parameters of spraying have a positive influence on the structure, properties, and quality assurance of multicomponent coatings. It is shown that the introduction of silicon and boron contributes the formation of hard-alloy high-temperature compounds with increased wear resistance. The maximum microhardness corresponds to the Cr-Si coatings with ~ 28 % titan content. In addition, the mechanical properties of the obtained material are improved by additional alloying of ~ 22 % silicon and bor. In turn, the coatings plating at a working gas flow rate in a ratio for acetylene ~ (20/25) l/min and oxygen ~ (22/27) l/min provides the chemical composition and spraying process parameters permanence as well as constant properties of coatings. The obtained results show that for the coatings of FeAl2-Ti-Si-B system at loading 5.0 MPa, sliding speed 1.5 m/s, and temperature up to 650 °C the stable performance of structural adaptability, which ensures the friction and wear parameters minimization, is demonstrated. The metallographic analysis and strip chart recording of specimens indicate that the friction surfaces are characterized by the absence of visible defects; the separate cold-welded regions are located in thin-film surface layers. The composition, structure, and tribological durability of coatings produced from the elements of the country's resource base were studied; their high adhesion, physical and mechanical characteristics and wear resistance under high-temperature conditions were defined. The thin-film surface structure patterns and properties were investigated with the help of modern physical and chemical methods of analysis. It was determined that the combination of mechanical, physical, and chemical properties of the investigated coatings provides vide opportunities for their usage as effective materials under high-temperature wear conditions. According to the test results, the application of the investigated composite coatings for friction unit efficiency improvement provides their operational reliability in accordance with requirements and opportunities that appear with the development of a new competitive material for wear-resistant coatings obtained with the help of the detonation method. Keywords: detonation coating: wear resistance, surface layer, structural adaptability, temperature.
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