ExperimentalInorganic fullerene-like WS 2 nanoparticles were synthesized using WO 3 powders as a precursor materials by a solid-gas reaction according to a procedure described elsewhere. [21] WS 2 particles (platelets of the 2H polytype) with average size of between 600±1700 nm were purchased from Aldrich. Electroless Ni-based composite coatings were deposited on the surface of the test ring and block fabricated from a mild carbon steel by electroless co-deposition. The bath compositions and conditions for the electroless coatings are: nickel sulfate 20±25 g/L, sodium hypophosphite 20±25g/L, sodium acetate 10±15 g/L, acetic acid 5±10 mL/L, surface agent 200±400 mg/L, IF-WS 2 , 2H-WS 2 , graphite or 6H-SiC 6.0 g/L, pH = 4.5±5.1, temperature at 80±85 C. Ni-P coating was firstly deposited for 0.5 h and then Ni-P-(IF-WS 2 ) was deposited for 2.5 h. For comparison, the Ni-P, Ni-P-SiC, Ni-P-(2H-WS 2 ) and Ni-P-graphite coatings were deposited on the test ring and block according to a similar procedure. The crystal structures of the as-prepared electroless composite coatings were analyzed by XRD (Philips X Pert MPD, Cu K a1 ). In this work, the electroless Ni-P-based composite coatings were treated at 673 K for 2 h in vacuum.The wear and friction parameters of the electroless composite coatings were measured using a MHK 500 ring-on-block friction testing machine, whose friction pairs consist of rotation ring (diameter in 49.24 mm, thickness in 13.00 mm) and static block (12.35 mm 12.35 mm 19.00 mm). The main axis rotation speed is 800 r/min, and 46# lubricant oil was used as lubricant. After running in at a load of 200 N for 20 min, the mass loss and friction coefficient were measured at a fixed load of 700 N, testing time last for 6 h. The wear resistance was evaluated according to the mass loss of the block specimen after wear testing. The worn surfaces of the electroless composite coatings on the blocks were observed by SEM (JEOL JSM-5600LV).