“…The first phase was about 15 -20 min, which is longer than the 3 -5 min observed in the case of immobilized biosorbent. As it has been reported earlier (10,20), the functional groups on the biosorbent may be modified after immobilization, and hence the role of the HO-groups in the process of metal ions biosorption may be increased. Thus, PVA-immobilized biomass had higher surface area than free cells and shorter time was needed for the first phase of the process.…”
Section: Kinetic Studies On the Biosorption Processmentioning
Nomenclature:W: a swelling degree of the hydrogel (%); w 0 : a weight of the dry sample (g); w: a weight of the swollen sample (g); t: a contact time (min); q e : an equilibrium uptake value (mg/g); k 2 : the second order rate constant (1/min); h: the initial sorption rate (mg/g/min); q: a metal uptake value at any time (mg/g); V: a reaction volume (l); C i : an initial metal concentration (mg/l); C f : a residual metal concentration (mg/l); m: the amount of dry biosorbent (g/l); R 2: correlation coefficient; q (total): total sorption capacity for the tertiary mixture (mg/g)
“…The first phase was about 15 -20 min, which is longer than the 3 -5 min observed in the case of immobilized biosorbent. As it has been reported earlier (10,20), the functional groups on the biosorbent may be modified after immobilization, and hence the role of the HO-groups in the process of metal ions biosorption may be increased. Thus, PVA-immobilized biomass had higher surface area than free cells and shorter time was needed for the first phase of the process.…”
Section: Kinetic Studies On the Biosorption Processmentioning
Nomenclature:W: a swelling degree of the hydrogel (%); w 0 : a weight of the dry sample (g); w: a weight of the swollen sample (g); t: a contact time (min); q e : an equilibrium uptake value (mg/g); k 2 : the second order rate constant (1/min); h: the initial sorption rate (mg/g/min); q: a metal uptake value at any time (mg/g); V: a reaction volume (l); C i : an initial metal concentration (mg/l); C f : a residual metal concentration (mg/l); m: the amount of dry biosorbent (g/l); R 2: correlation coefficient; q (total): total sorption capacity for the tertiary mixture (mg/g)
“…Esterication of the hydroxyl groups: 5 g of raw biomass was suspended in 30 mL mixture of pyridine and acetic anhydride (12 to 88 volume ratio) and heated for 2 h at 60 C. The treatment was widely applied for determination of hydroxyl content of carboxylic acids. 16 The biomass samples obtained were labeled as 'd'. The reaction occurs as follows:…”
Section: Chemical Modication Experimentsmentioning
Palladium uptake process, multi-scale visualization and functional groups of Providencia vermicola biomass in palladium biosorption were analyzed for the first time.
“…Removal was considered strongly dependent on pH, on the amount of biomass and on the concentration of Cu ions in the solutions. The biosorption process was fast and, in the first 5 min, up to 75% of the total Cu ions were deposited on the surface of the fungus under study (Tsekova et al 2006).…”
Section: Trace Element Removal Test In Aerobic Biofiltersmentioning
Remo brasi line Ramal Coffee bea can be detr Aspergillus Mn and Zn emerged as unpolluted immobilized and A. bras from unpol conducted differently t fungus P. biofilters (4 and 41.6%, treatments.
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