Heteroadamantanes and their derivatives

Кузнецов, А. И.; Sokolova, T. D.; Vladimirova, I. A.; Serova, T. M.; D'yakov, M. Yu.; Shundrin, Leonid A.; Moskovkin, A. S.; Unkovskii, B. V.

doi:10.1007/bf00475254

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2016

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“…Bispidine-type ligands can be easily modified to fulfill a task of attaching to the desired vector of biological object. Indeed, these molecules possess at least two sites that can be used for conjugation with biomolecules (see Figure , bottom right): (a) if X = OH and Y = H, then the hydroxyl could be modified to carbamate or propargyl ether moieties; if XY = O, then the carbonyl could be reduced to a hydroxyl moiety and all of the possibilities for hydroxyl functionalization are then applied; moreover, the bispidinic carbonyl group is known to form hydantoins. − (b) R groups could have linkable residues like SH, COOH, OH, and so on.…”

Section: Introductionsupporting

confidence: 58%

Copper–Bispidine Complexes: Synthesis and Complex Stability Study

et al. 2016

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A new series of dicarboxylic derivatives of bispidines have been synthesized to develop novel copper(II) complexes suitable as imaging agents for positron emission tomography. For characterization purposes, copper complexes of bispidines were synthesized in the pure form and in quantitative yields by neutralization of ligands with malachite. The formation of complexes and their stoichiometries were studied by potentiometric titration, cyclic voltammetry, and spectroscopic methods. The stability constants were found to be fairly suitable for copper cation fixation inside dianionic chelate molecules.

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