Heteroelement organobismuth compounds in 2010–2020: A review

Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand

“…These attributes have been effectively leveraged in catalytic applications in recent years. 14–20 PBiP pincer ligands featuring a neutral Bi( iii )R 3 moiety have mainly been reported to act as L-type or X-type ligands to transition metal centres utilising Bi(6s) or Bi(6p) orbitals, respectively (Fig. 1).…”