2013
DOI: 10.1007/s10562-013-1057-8
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Heterogeneous Cyanation Reaction of Aryl Halides Catalyzed by a Reusable Palladium Schiff Base Complex in Water

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Cited by 12 publications
(5 citation statements)
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“…In 2013, palladium as a polymer aided macrocyclic palladium complex was utilized for the synthesis of various benzonitriles from a range of iodo and bromo arenes. 36 The reaction was performed in water in the presence of Triton X-100 as non-ionic surfactant and avoided the use of any organic solvents (Scheme 2). The synthesis was compatible with the electronic effects and the steric effects exerted by the substituents on the aryl halides.…”
Section: Introductionmentioning
confidence: 99%
“…In 2013, palladium as a polymer aided macrocyclic palladium complex was utilized for the synthesis of various benzonitriles from a range of iodo and bromo arenes. 36 The reaction was performed in water in the presence of Triton X-100 as non-ionic surfactant and avoided the use of any organic solvents (Scheme 2). The synthesis was compatible with the electronic effects and the steric effects exerted by the substituents on the aryl halides.…”
Section: Introductionmentioning
confidence: 99%
“…Our catalytic system is also compared (Supporting Information, Table S1) with reported Pd containing catalytic systems for cyanation of aryl halides. The comparison table shows that most of the reported Pd catalysts are homogeneous in nature, use phosphine ligands, and possess high Pd content. However, the main disadvantage of using homogeneous catalysts is reusability.…”
Section: Resultsmentioning
confidence: 99%
“…Thus, a more efficient and convenient protocol for this important transformation would be appreciated and hence in recent years, considerable attention has been paid to the development of Pd NPs with improved catalytic properties in cyanation reactions. [48][49][50][51][52][53] The most common problems associated with nanocatalysts are tedious filtration and centrifugation protocols. Additionally NPs undergo agglomeration without the addition of stabilizers, thereby diminishing their activity.…”
Section: Introductionmentioning
confidence: 99%
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“…Until now, various reports have been presented about the use of ligands in the cyanidation reaction, and by examining the used ligands and the importance of ligands containing nitrogen and oxygen in binding to various metals and forming stable complexes, 27–30,19 a we chose vitamin B 5 as a suitable ligand for this reaction.…”
Section: Introductionmentioning
confidence: 99%