Heterogeneous Fenton-like Catalyzation of Nanoscale Schwertmannite for Sulfamethoxazole Degradation

Abstract

Sulfamethoxazole (SMX) contamination in large quantities of wastewater can cause potential environmental problems. Due to difficulty in degrading SMX by natural processes, it is necessary to develop a novel technology to solve this problem. Advanced oxidation processes (AOPs) have been identified as methods with a high potential to treat recalcitrant organic pollutants. The nanoscale schwertmannite (nano-SWT) was prepared with an indoor-temperature synthesis method facilitated by polyvinylpyrrolidone (PVP). In this study, we performed a reaction of the nano-SWT materials with Fenton-like catalysts for SMX degradation in hydrogen peroxide (H2O2) media. The findings showed that the nano-SWT prepared by addition of 0.1 g·L−1 PVP (nano-SWT-n, n = 0.1) could degrade 92.5% of the SMX within 90 min at indoor temperature, which was due to the nano-SWT providing abundant reaction sites at the solid/solution interfaces. Additionally, SMX could be highly mineralized with 75% TOC removal and H2O2 was efficiently utilized during the nano-SWT/H2O2 process. In addition, after six cycles of Fenton-like degradation, the nano-SWT remained stable and reusable as a Fenton-like catalyst for SMX degradation. The nano-SWT performed well as a catalyst for SMX degradation. Additionally, this work provides a feasible environmental purification approach for the efficient degradation of SMX through the use of nanoscale schwertmannite as a catalyst in heterogeneous Fenton-like systems.

Special Issue: Functional Nanoparticles for Environmental Contaminants Removal and Agricultural Application

“…Additionally, Liu et al (2022) found that Sedum plumbizincicola nanoparticles can effectively remove Bisphenol A (BPA) from complex wastewater, demonstrating stable and efficient reactions [29]. Nanoscale schwertmannite (nano-SWT) was prepared using an indoor temperature synthesis method with the assistance of polyvinylpyrrolidone, and nano-SWT was found to be effective in reducing sulfamethoxazole in the presence of Fenton-like catalysts using hydrogen peroxide (H 2 O 2 ) [30]. Currently, Fenton catalysts are widely employed in conjunction with nanoparticles for environmental contaminant removal.…”