Heterogeneous So2-Oxidation in the Droplet Phase

Beilke, S.; Gravenhorst, G.

doi:10.1016/b978-0-08-022932-4.50025-2

Cited by 36 publications

(40 citation statements)

References 29 publications

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“…Equilibrium between so 2 in the gas phase and sulfur (IV) in the droplet is several orders of magnitude faster than oxidation of sulfur (IV) to sulfate [56]. Similar assumptions were made regarding NH 3 and co 2 gases.…”

Section: Catal Ismentioning

confidence: 67%

Chemical and Catalytic Properties of Elemental Carbon

et al. 1982

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Section: Catal Ismentioning

confidence: 67%

Chemical and Catalytic Properties of Elemental Carbon

et al. 1982

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“…The equilibrium concentrations of the sulphite species at the pH values used in our experiments were calculated by using the dissociation Constants at 25~ given by Beilke & Gravenhorst (1978) (Table 2).…”

Section: Discussionmentioning

confidence: 99%

Toxicity of root-applied sulphite in Zea mays

Bertelsen

Gissel‐Nielsen

1987

Environ Geochem Health

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Zea mays was grown in nutrient solution with different concentrations of sulphite and sulphate (0, 5, and 10 mM) at pH 5 or 7, with or without aeration, for five days. Sulphite injured the plants, especially at low pH. Lack of aeration increased the sulphite injury of the plants at the high pH. in the aerated solutions, sulphite concentrations approached zero after five hours, while the unaerated solutions still contained sulphite after four days. Very little sulphite was found in the plants. The results indicate that the toxicity to the plants of the different chemical species of the sulphite in the solution decreases in the following order: SO2 (aq) > HSO3 (-) > SO3 (2-).

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“…The reaction of the sorbed SO 2 may proceed via metal-sulfitocomplexes, with HO 2 and SO 3-as chain carriers [Beilke and Gravenhorst, 1978]. In addition, SO2 may be oxidized by ozone [Maahs, 1983].…”

Section: So X Chemistry On Dustmentioning

confidence: 99%

Long‐range transport of SO_x and dust in East Asia during the PEM B Experiment

Xiao¹,

Carmichael²,

Durchenwald³

et al. 1997

J. Geophys. Res.

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Abstract. The transport of SO2 and surfate in East Asia (including eastern China, Korea, and Japan) during the period of March 1 through March 14, 1994, is studied using a three-dimensional regional-scale atmospheric chemistry model. This period corresponds to that in which the Pacific Exploratory Mission in the Western Pacific Ocean (PEM-West B) was being conducted around Japan. During this period, characterized by the passage of cold fronts and relatively dry conditions, the anthropogenic sulfur emitted from the source regions in East Asia is transported out into the central Pacific Ocean. The sulfur transport is largely limited to the lower 4 km of the atmosphere, with the maximum flux occurring in the 30 ø to 40øN latitude band containing the bulk of the anthropogenic emissions. The interactions between the sulfur cycle and mineral aerosol are also included in the analysis. It is found that the chemical conversion of SO2 to sulfate in the presence of mineral aerosol may be a significant process during this time period, and may contribute from 20% to 40% of the total sulfate production. Sulfur dioxide arising from volcanic sources in Japan is also discussed.

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Heterogeneous So2-Oxidation in the Droplet Phase

Cited by 36 publications

References 29 publications

Chemical and Catalytic Properties of Elemental Carbon

Chemical and Catalytic Properties of Elemental Carbon

Toxicity of root-applied sulphite in Zea mays

Long‐range transport of SO_x and dust in East Asia during the PEM B Experiment

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Heterogeneous So2-Oxidation in the Droplet Phase

Cited by 36 publications

References 29 publications

Chemical and Catalytic Properties of Elemental Carbon

Chemical and Catalytic Properties of Elemental Carbon

Toxicity of root-applied sulphite in Zea mays

Long‐range transport of SOx and dust in East Asia during the PEM B Experiment

Contact Info

Product

Resources

About

Long‐range transport of SO_x and dust in East Asia during the PEM B Experiment